Department of Material Science, Graduate School of Science and Technology, Shinshu University, Matsumoto 390-8621, Japan.
Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan.
Int J Mol Sci. 2020 Sep 25;21(19):7087. doi: 10.3390/ijms21197087.
Azulene derivatives with heterocyclic moieties in the molecule have been synthesized for applications in materials science by taking advantage of their unique properties. These derivatives have been prepared by various methods, involving electrophilic substitution, condensation, cyclization, and transition metal-catalyzed cross-coupling reactions. Herein, we present the development of the synthetic methods, reactivities, and physical properties for the heterocycle-substituted and heterocycle-fused azulenes reported in the last decade.
为了在材料科学领域的应用，人们已经合成了具有杂环结构的薁衍生物，利用其独特的性质。这些衍生物是通过各种方法制备的，包括亲电取代、缩合、环化和过渡金属催化的交叉偶联反应。在此，我们介绍了过去十年中报道的取代和稠合有杂环的薁衍生物的合成方法、反应活性和物理性质的发展。
