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导电中性金双二硫纶配合物[Au(dspdt)]˙。

Conducting neutral gold bisdithiolene complex [Au(dspdt)]˙.

作者信息

Velho Mariana F G, Silva Rafaela A L, Brotas Graça, Lopes Elsa B, Santos Isabel C, Charas Ana, Belo Dulce, Almeida Manuel

机构信息

Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, E.N. 10, P-2695-066 Bobadela LRS, Portugal.

Instituto de Telecomunicações, Instituto Superior Técnico, Av. Rovisco Pais 1, P-1049-001, Lisboa, Portugal.

出版信息

Dalton Trans. 2020 Oct 12;49(39):13737-13743. doi: 10.1039/d0dt02931a.

Abstract

[Au(dspdt)2] (dspdt = 2,3-dihydro-5,6-selenophenedithiolate) is an unprecedented example of a neutral gold bisdithiolene complex with a unique structure composed of interacting dimer and trimer chains displaying relatively high electrical conductivity (0.1 S cm-1 at room temperature).

摘要

[Au(dspdt)₂](dspdt = 2,3 - 二氢 - 5,6 - 硒吩二硫醇盐)是一种前所未有的中性金双硫烯配合物,其独特结构由相互作用的二聚体和三聚体链组成,显示出相对较高的电导率(室温下为0.1 S cm⁻¹)。

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