用于合成具有中性金属节点的稳定多孔分子导体的初步化学还原。
Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes.
作者信息
Koyama Shohei, Tanabe Tappei, Takaishi Shinya, Yamashita Masahiro, Iguchi Hiroaki
机构信息
Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai, Miyagi 980-8578, Japan.
出版信息
Chem Commun (Camb). 2020 Nov 7;56(86):13109-13112. doi: 10.1039/d0cc03541f. Epub 2020 Oct 1.
PMID:33000779
Abstract
Preliminary chemical reduction of naphthalenediimide (NDI)-based organic ligands was applied to the synthesis of a porous molecular conductor (PMC) with neutral metal nodes (cobalt(ii) acetylacetonate). The obtained semiconductive PMC (PMC-2) was stable due to the neutral metal nodes, providing an advantage over electrochemical reduction.
摘要
将萘二亚胺（NDI）基有机配体的初步化学还原应用于具有中性金属节点（乙酰丙酮钴（II））的多孔分子导体（PMC）的合成。由于中性金属节点，所获得的半导电PMC（PMC-2）很稳定，这比电化学还原具有优势。
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