扭曲多环芳烃的氢键有机框架。
Hydrogen-bonded organic frameworks of twisted polycyclic aromatic hydrocarbon.
机构信息
Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan.
Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
出版信息
Chem Commun (Camb). 2020 Nov 3;56(87):13369-13372. doi: 10.1039/d0cc06081j.
PMID:33030481
Abstract
A dibenzo[g,p]chrysene (DBC)-based hydrogen-bonded organic framework (HOF) was constructed by shape-fitted docking of the twisted π-conjugated core. The activated HOF, possessing exactly eclipsed stacking of the DBC cores, (CPDBC-1a) had a BET surface area of 1548 m2 g-1 and possessed photoconductivity.
摘要
一种基于二苯并[g,p]色烯（DBC）的氢键有机框架（HOF）通过扭曲的π共轭核的形状匹配对接构建而成。活化的 HOF，具有完全重叠的 DBC 核堆叠，（CPDBC-1a）具有 1548 m2 g-1 的 BET 表面积和光电导性。
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