Inorganic Chemistry I, Ruhr-Universität Bochum Universitätsstrasse 150, 44780 Bochum, Germany.
Phys Chem Chem Phys. 2020 Oct 21;22(40):23307-23314. doi: 10.1039/d0cp04010j.
Most porous polymers are notoriously hard to characterize due to their amorphous and completely insoluble nature. On the other hand, they are an interesting class of materials for sorption, catalytic, and electrode applications, thus they warrant in-depth studies. In this contribution, we elaborate on the possibilities that dynamic nuclear polarization offers towards the investigation of the structure of porous polymers. We discuss the advantages and disadvantages of this technique in the investigation of model polymers.
大多数多孔聚合物由于其无定形和完全不溶的性质而难以进行表征。另一方面，它们是一类用于吸附、催化和电极应用的有趣材料，因此值得进行深入研究。在本贡献中，我们详细阐述了动态核极化在研究多孔聚合物结构方面提供的可能性。我们讨论了该技术在模型聚合物研究中的优缺点。
