Synthesis and electron-transport properties of a stable antiaromatic Ni norcorrole with the smallest -substituent.

meso-Dimethylnorcorrole NiII complex exhibited enough stability under ambient conditions despite the distinct antiaromaticity. The small methyl substituents realized a dense and long-range π-stacking in its solid state, which resulted in the superior electron-transporting ability to previously reported NiII norcorroles.