Ukai Shusaku, Koo Yun Hee, Fukui Norihito, Seki Shu, Shinokubo Hiroshi
Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan.
Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.
Dalton Trans. 2020 Oct 27;49(41):14383-14387. doi: 10.1039/d0dt03143g.
meso-Dimethylnorcorrole NiII complex exhibited enough stability under ambient conditions despite the distinct antiaromaticity. The small methyl substituents realized a dense and long-range π-stacking in its solid state, which resulted in the superior electron-transporting ability to previously reported NiII norcorroles.
尽管具有明显的反芳香性，但内消旋二甲基降卟啉镍（II）配合物在环境条件下仍表现出足够的稳定性。小的甲基取代基在其固态中实现了密集且长程的π堆积，这导致其电子传输能力优于先前报道的镍（II）降卟啉。
