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具有高度发达的BET比表面积的纳米石墨颗粒改性的奥氏体不锈钢AISI 316L的烧结动力学

Sintering Kinetics of Austenitic Stainless Steel AISI 316L Modified with Nanographite Particles with Highly Developed BET Specific Surface Area.

作者信息

Kozub Barbara, Kazior Jan, Szewczyk-Nykiel Aneta

机构信息

Faculty of Materials Engineering and Physics, Institute of Materials Engineering, Cracow University of Technology, Al. Jana Pawła II 37, 31-864 Cracow, Poland.

出版信息

Materials (Basel). 2020 Oct 14;13(20):4569. doi: 10.3390/ma13204569.

Abstract

The subject of this work was the study of processes occurring during sintering of water atomized AISI 316L austenitic stainless steel powder modified by the addition of graphite nanoparticles. The main purpose of the work was to determine the effect of modification of the AISI 316L stainless steel austenitic powder by the addition of graphite nanopowder on the sintering kinetics and oxide reduction mechanism. The phenomena occurring during the sintering process and oxide reduction mechanisms were subjected to detailed characterizations. Mixtures with two types of nanopowder with a high BET (measurement technique of the specific surface area of materials based on Brunauer-Emmett-Teller theory) specific surface area of 350 and 400 m/g and for comparison with graphite micropowder with a poorly developed BET specific surface area of 15 m/g were tested. The conducted thermal analysis showed that the samples made of austenitic stainless steel doped with 0.2% and 0.3% by weight graphite nanopowder with a BET specific surface area of 400 m/g, sintered best the oxide reduction reactions, with a more intensive participation of carbon, for these samples.

摘要

这项工作的主题是研究添加石墨纳米颗粒改性的水雾化AISI 316L奥氏体不锈钢粉末在烧结过程中发生的过程。该工作的主要目的是确定添加石墨纳米粉末对AISI 316L不锈钢奥氏体粉末进行改性对烧结动力学和氧化物还原机制的影响。对烧结过程中发生的现象和氧化物还原机制进行了详细表征。测试了两种具有高BET(基于布鲁瑙尔-埃米特-泰勒理论的材料比表面积测量技术)比表面积分别为350和400 m²/g的纳米粉末混合物,并与BET比表面积为15 m²/g且比表面积发展较差的石墨微粉进行比较。进行的热分析表明,由掺杂0.2%和0.3%(重量)BET比表面积为400 m²/g的石墨纳米粉末的奥氏体不锈钢制成的样品,氧化物还原反应烧结效果最佳,对于这些样品,碳的参与更为强烈。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9399/7602268/fc9c6e889179/materials-13-04569-g001.jpg

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