Chakraborty Soumi, Das Arpan, Ahmed Jasimuddin, Barman Sayani, Mandal Swadhin K
Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur Campus, Nadia, 741246, West Bengal, India.
Chem Commun (Camb). 2020 Nov 18;56(89):13788-13791. doi: 10.1039/d0cc05348a. Epub 2020 Oct 19.
Herein, we report the synthesis of a Cr(iii)-complex bearing a redox non-innocent phenalenyl-based ligand and its use as a catalyst for SET mediated hydrosilylative reduction of carbon dioxide towards formylation of primary amides under mild conditions. A preliminary mechanistic picture for this transformation has been proposed by isolation and characterization of several reactive intermediates.
在此，我们报道了一种带有氧化还原非惰性苝基配体的Cr(iii)配合物的合成及其在温和条件下作为单电子转移介导的二氧化碳氢硅化还原反应催化剂用于伯酰胺甲酰化反应的应用。通过分离和表征几种反应中间体，提出了该转化反应的初步机理。
