Department of Basic Sciences, Kermanshah University of Technology, Kermanshah, Iran.
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Iran.
Talanta. 2021 Jan 1;221:121648. doi: 10.1016/j.talanta.2020.121648. Epub 2020 Sep 15.
Development of magnetic nanomaterials has greatly promoted the innovation of in-tube solid-phase microextraction. This review article gives an insight into recent advances in the modifications and applications of magnetic nanomaterials for in-tube solid-phase microextraction. Also, different magnetic nanomaterials which have recently been utilized as in-tube solid-phase microextraction sorbents are classified. This study shows that magnetic nanomaterials have gained significant attention owing to large specific surface area, selective absorption, and surface modification. Magnetic in-tube solid-phase microextraction has been applied for the analysis of food samples, biological, and environmental. However, for full development of magnetic in-tube SPME, effort is still needed to overcome limitations, such as mechanical stability, selectivity and low extraction efficiency. To achieve these objectives, research on magnetic in-tube SPME is mainly focused in the preparation of new extractive phases.
磁性纳米材料的发展极大地促进了管内固相微萃取的创新。本文综述了磁性纳米材料在管内固相微萃取中的修饰和应用的最新进展。此外,对最近用作管内固相微萃取吸附剂的不同磁性纳米材料进行了分类。研究表明,磁性纳米材料由于具有较大的比表面积、选择性吸附和表面修饰而受到广泛关注。磁管内固相微萃取已应用于食品样品、生物和环境分析。然而,为了充分发展磁管内固相微萃取,仍需要努力克服机械稳定性、选择性和低萃取效率等限制。为了实现这些目标,磁管内固相微萃取的研究主要集中在新萃取相的制备上。