Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, CanadaB3H 4R2.
Chem Soc Rev. 2020 Nov 21;49(22):8335-8353. doi: 10.1039/d0cs00476f. Epub 2020 Oct 20.
Diazaphospholenes have recently emerged as main-group hydride transfer catalysts. This review will briefly summarize the common structural variants of diazaphospholenes, and the properties that make them superb hydride transfer catalysts, followed by a critical examination of the various preparative routes toward diazaphospholenes. Finally, an in-depth examination of the reactivity of diazaphospholenes in contemporary catalysis, including asymmetric catalysis will be undertaken.
二氮杂环戊烯类化合物最近已成为主要的氢化物转移催化剂。本综述将简要总结二氮杂环戊烯类化合物的常见结构变体，以及使它们成为出色的氢化物转移催化剂的特性，然后对制备二氮杂环戊烯类化合物的各种途径进行批判性考察。最后，将深入研究二氮杂环戊烯类化合物在当代催化反应（包括不对称催化）中的反应性。
