Yang Xin-Xue, Yu Wei-Dong, Yi Xiao-Yi, Li Lei-Jiao, Liu Chao
Hunan Provincial Key Laboratory of Chemical Power Sources, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, P. R. China.
Chem Commun (Camb). 2020 Nov 21;56(90):14035-14038. doi: 10.1039/d0cc05336h. Epub 2020 Oct 26.
A carboxylate-driven assembly strategy has been developed for the first time to build calix[n]arene-based polyoxotitanate clusters with tuneable nuclearity and structures. Photocatalytic studies revealed that these clusters exhibit structural-dependent H evolution ability with a maximum rate up to 415.11 μmol h g, which is almost the highest recorded in polyoxotitanate clusters.
首次开发了一种由羧酸盐驱动的组装策略，用于构建具有可调节核数和结构的基于杯[n]芳烃的聚氧化钛簇。光催化研究表明，这些簇表现出与结构相关的析氢能力，最大速率高达415.11 μmol h g，这几乎是聚氧化钛簇中记录的最高值。
