Hwang Hyuntae, Ma Kyung Yeol, Kim Jae Won, Yuk Dohun, Hong Jiwon, Jung Jun Hyuk, Yong Seok-Min, Choi Jaeho, Kim Jin Young, Shin Hyeon Suk
Department of Energy Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.
Nanoscale. 2020 Nov 5;12(42):21895-21900. doi: 10.1039/d0nr06333a.
Anti- and de-icing heating systems are used to both prevent the accumulation of ice and to remove it and thus avoid damage. Typically, anti- and de-icing heating systems employ carbon-based materials, metal frames, and bulky ceramic structures. These structures generally lead to the loss of radio-frequency (RF) signals and are also relatively heavy. Therefore, RF equipment such as radar domes (radomes) and antennas require anti- and de-icing systems with high RF transmittance for normal operation. In this work, we fabricated a fluorine-doped tin oxide (FTO) wave pattern covered with hexagonal boron nitride (h-BN) layers (i.e., an h-BN/FTO wave pattern) on a glass substrate for use as an RF-transmitting heating system for anti- and de-icing. The FTO wave pattern and h-BN layer act as the heating element and heat spreader, respectively. The h-BN layer showed a transmittance of approximately 90% for RF waves on glass (X band: 8.2-12.4 GHz) (the 10% loss was attributable to the glass substrate). The differences in the temperatures of the FTO-patterned and non-patterned areas for the h-BN(3.6 nm)/FTO and FTO wave pattern were 19.3 and 25.5 °C, respectively. This means that the h-BN layer improved the heat-spreading performance by 6.2 °C. Furthermore, a de-icing test was performed using the h-BN(3.6 nm)/FTO wave pattern by applying a voltage of 40 V at -20 °C. The ice on the non-patterned area melted within 1 min while that on the FTO-patterned area melted within 30 s. These results suggest that the fabricated h-BN(3.6 nm)/FTO wave pattern for RF-transmitting heating systems is suitable for use with the radomes of drones, unmanned aerial vehicles, aircraft, and spaceships in extremely cold environments.
防冰和除冰加热系统用于防止冰的积聚并去除冰,从而避免损坏。通常,防冰和除冰加热系统采用碳基材料、金属框架和笨重的陶瓷结构。这些结构通常会导致射频(RF)信号的损失,并且也相对较重。因此,诸如雷达罩(天线罩)和天线之类的射频设备需要具有高射频透射率的防冰和除冰系统才能正常运行。在这项工作中,我们在玻璃基板上制造了一种覆盖有六方氮化硼(h-BN)层的氟掺杂氧化锡(FTO)波形图案(即h-BN/FTO波形图案),用作防冰和除冰的射频传输加热系统。FTO波形图案和h-BN层分别充当加热元件和热扩散器。h-BN层在玻璃上对射频波(X波段:8.2-12.4 GHz)的透射率约为90%(10%的损耗归因于玻璃基板)。对于h-BN(3.6 nm)/FTO和FTO波形图案,FTO图案化区域和非图案化区域的温度差分别为19.3和25.5°C。这意味着h-BN层将热扩散性能提高了6.2°C。此外,通过在-20°C下施加40 V的电压,使用h-BN(3.6 nm)/FTO波形图案进行了除冰测试。非图案化区域的冰在1分钟内融化,而FTO图案化区域的冰在30秒内融化。这些结果表明,所制造的用于射频传输加热系统的h-BN(3.6 nm)/FTO波形图案适用于极寒环境下的无人机、无人驾驶飞行器、飞机和宇宙飞船的天线罩。