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基于咪唑鎓的离子液体作为黏土膨胀抑制剂：作用机制、性能评价及不同阴离子的影响

Imidazolium-Based Ionic Liquids as Clay Swelling Inhibitors: Mechanism, Performance Evaluation, and Effect of Different Anions.

作者信息

Ahmed Khan Rizwan, Murtaza Mobeen, Abdulraheem Abdulazeez, Kamal Muhammad Shahzad, Mahmoud Mohamed

机构信息

Petroleum Engineering Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia.

Center for Integrative Petroleum Research, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia.

出版信息

ACS Omega. 2020 Oct 6;5(41):26682-26696. doi: 10.1021/acsomega.0c03560. eCollection 2020 Oct 20.

DOI:10.1021/acsomega.0c03560
PMID:33110995
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7581242/
Abstract

Clay swelling is one of the challenges faced by the oil industry. Water-based drilling fluids (WBDF) are commonly used in drilling operations. The selection of WBDF depends on its performance to improve rheology, hydration properties, and fluid loss control. However, WBDF may result in clay swelling in shale formations during drilling. In this work, the impact of imidazolium-based ionic liquids on the clay swelling was investigated. The studied ionic liquids have a common cation group, 1-allyl-3-methyllimidozium, but differ in anions (bromide, iodide, chloride, and dicyanamide). The inhibition behavior of ionic liquids was assessed by linear swell test, inhibition test, capillary suction test, rheology, filtration, contact angle measurement, scanning electron microscopy, and X-ray diffraction (XRD). It was observed that the ionic liquids with different anions reduced the clay swelling. Ionic liquids having a dicyanamide anion showed slightly better swelling inhibition performance compared to other inhibitors. Scanning electron microscopy images showed the water tendency to damage the clay structure, displaying asymmetrical cavities and sharp edges. Nevertheless, the addition of an ionic liquid to sodium bentonite (clay) exhibited fewer cavities and a smooth and dense surface. XRD results showed the increase in d-spacing, demonstrating the intercalation of ionic liquids in interlayers of clay. The results showed that the clay swelling does not strongly depend on the type of anion in imidazolium-based ILs. However, the type of anion in imidazolium-based ILs influences the rheological properties. The performance of ionic liquids was compared with that of the commonly used clay inhibitor (sodium silicate) in the oil and gas industry. ILs showed improved performance compared to sodium silicate. The studied ionic liquids can be an attractive alternative for commercial clay inhibitors as their impact on the other properties of the drilling fluids was less compared to commercial inhibitors.

摘要

粘土膨胀是石油工业面临的挑战之一。水基钻井液（WBDF）常用于钻井作业。WBDF的选择取决于其改善流变学、水化特性和滤失控制的性能。然而，WBDF在钻井过程中可能会导致页岩地层中的粘土膨胀。在这项工作中，研究了基于咪唑鎓的离子液体对粘土膨胀的影响。所研究的离子液体具有共同的阳离子基团1-烯丙基-3-甲基咪唑鎓，但阴离子不同（溴化物、碘化物、氯化物和双氰胺）。通过线性膨胀试验、抑制试验、毛细管吸入试验、流变学、过滤、接触角测量、扫描电子显微镜和X射线衍射（XRD）评估离子液体的抑制行为。观察到不同阴离子的离子液体减少了粘土膨胀。与其他抑制剂相比，具有双氰胺阴离子的离子液体表现出略好的膨胀抑制性能。扫描电子显微镜图像显示水有破坏粘土结构的趋势，呈现出不对称的空洞和尖锐边缘。然而，向钠膨润土（粘土）中添加离子液体后，空洞较少，表面光滑致密。XRD结果显示d间距增加，表明离子液体插入了粘土层间。结果表明，粘土膨胀并不强烈依赖于基于咪唑鎓的离子液体中的阴离子类型。然而，基于咪唑鎓的离子液体中的阴离子类型会影响流变性能。将离子液体的性能与石油和天然气工业中常用的粘土抑制剂（硅酸钠）进行了比较。与硅酸钠相比，离子液体表现出更好的性能。所研究的离子液体可以成为商业粘土抑制剂的有吸引力的替代品，因为与商业抑制剂相比，它们对钻井液其他性能的影响较小。

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