Shen Cheng, Liu Fu-Wen, Wu Jian, Huang Shen-Fa, Wang Min, Huang Bo-Tao
Shanghai Academy of Environmental Sciences, Shanghai 200233, China.
State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, School of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China.
Huan Jing Ke Xue. 2020 Nov 8;41(11):5125-5132. doi: 10.13227/j.hjkx.202003267.
Fifty typical redevelopment industrial sites in the Putuo, Baoshan, Minhang, and Jiangding districts of Shanghai were chosen to evaluate the ecological risk of heavy metals in the soil. The contents of heavy metal (Hg, Cd, Pb, Cr, and As) in 1847 soil samples, taken from vertical sections, were determined, and their risks were evaluated using the Nemero composite index and Hakanson potential ecological risk index. The average contents of Hg, Cd, Pb, Cr, and As in topsoil samples were 0.33, 0.37, 74.55, 69.23, and 9.05 mg·kg, respectively. The contents of Hg, Cd, and Pb exceeded the soil background values of Shanghai, which were 2.75, 2.85, and 2.93 times the background values, respectively. The contents of five heavy metals in soil decreased gradually with increased depth. The contents of heavy metals in deep and saturated soils were close to, or below, the background values, indicating that the anthropic activity disturbance was mainly confined to the topsoil. The accumulation of Hg, Cd, and Pb was the most obvious in Putuo topsoil, with the average contents being 4.25, 4.85, and 3.09 times the background values, respectively. The average contents of Hg and Pb in Baoshan were 4.92 and 6.43 times the background values, respectively. The Nemero Composite Index of Baoshan and Putuo districts were 3.70 and 3.20, respectively, representing heavy pollution level at these sites. The Hakanson potential ecological risk indexes of the Putuo and Baoshang districts were 398.59 and 303.08, respectively, with considerable ecological risk levels. The content and ecological risk of heavy metals at the Minhang and Jiading sites were relatively low. In summary, the pollution of heavy metal in the redeveloped industrial sites is influenced by the operating time, industry type, and past management level of the enterprises. The heavy metal accumulation in the Putuo and Baoshan districts, whose industries developed earlier, were higher than those in the Minhang and Jiading districts. The pollution of heavy metal Hg, Cd, and Pb in soil should be a focus of future work.
选取上海市普陀、宝山、闵行和嘉定4个区的50个典型再开发工业场地,对土壤中重金属的生态风险进行评价。测定了取自垂直剖面的1847个土壤样品中重金属(汞、镉、铅、铬和砷)的含量,并采用内梅罗综合指数和哈坎森潜在生态风险指数对其风险进行评价。表层土壤样品中汞、镉、铅、铬和砷的平均含量分别为0.33、0.37、74.55、69.23和9.05mg·kg。汞、镉和铅的含量超过了上海土壤背景值,分别是背景值的2.75、2.85和2.93倍。土壤中5种重金属含量随深度增加而逐渐降低。深层和饱和土壤中重金属含量接近或低于背景值,表明人为活动干扰主要局限于表层土壤。普陀区表层土壤中汞、镉和铅的积累最为明显,平均含量分别是背景值的4.25、4.85和3.09倍。宝山区汞和铅的平均含量分别是背景值的4.92和6.43倍。宝山区和普陀区的内梅罗综合指数分别为3.70和3.20,表明这些场地处于重度污染水平。普陀区和宝山区的哈坎森潜在生态风险指数分别为398.59和303.08,生态风险水平较高。闵行和嘉定场地的重金属含量和生态风险相对较低。综上所述,再开发工业场地的重金属污染受企业运营时间、行业类型和以往管理水平的影响。产业发展较早的普陀区和宝山区的重金属积累高于闵行区和嘉定区。土壤中重金属汞、镉和铅的污染应是今后工作的重点。