Lu Xuan, Zhang Rui-Qin, Han Luo-Kai
Research Institute of Environmental Science, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China.
Henan Broadcasting System 102, Zhengzhou 450002, China.
Huan Jing Ke Xue. 2020 Oct 8;41(10):4426-4435. doi: 10.13227/j.hjkx.201912192.
In this study, according to the activity levels of volatile organic compounds (VOCs) sources and source profiles, a 2016-based inventory of the speciation emission of the VOCs was established and the ozone formation potential (OFP) were estimated in Zhengzhou. The results showed that the total VOCs emission in Zhengzhou in 2016 was 96215.3 t. The highest emission source was on-road mobile source (29.7%) followed by solvent use sources (28.1%). The species that contributed the highest emission was alkanes (29.8%) followed by aromatics (29.0%). The OFP in Zhengzhou in 2016 was 341291.0 t with the highest contributing source as on-road mobile (30.5%) followed by solvent use source (28.8%). Moreover, the light duty gasoline vehicle, use of interior wall coatings, vehicle surface coating, gas station loading and unloading, and manufacture of non-metallic mineral were the major secondary emission sources of OFP, which needed to be controlled for reducing ozone pollution in Zhengzhou. For VOCs species group, the higher contribution groups were aromatics (42.8%) and alkenes (38.9%). The sources that produced -xylene, propylene, ethylene, and other species should be paid more attention.
在本研究中,根据挥发性有机化合物(VOCs)源的活性水平和源成分谱,建立了基于2016年的郑州市VOCs物种排放清单,并估算了臭氧生成潜势(OFP)。结果表明,2016年郑州市VOCs排放总量为96215.3吨。排放量最高的源是道路移动源(29.7%),其次是溶剂使用源(28.1%)。排放贡献最高的物种是烷烃(29.8%),其次是芳烃(29.0%)。2016年郑州市的OFP为341291.0吨,贡献最高的源是道路移动源(30.5%),其次是溶剂使用源(28.8%)。此外,轻型汽油车、内墙涂料使用、车辆表面涂装、加油站装卸以及非金属矿物制造是OFP的主要二次排放源,为减少郑州市的臭氧污染需要对其进行控制。对于VOCs物种组,贡献较高的组是芳烃(42.8%)和烯烃(38.9%)。应更加关注产生二甲苯、丙烯、乙烯等物种的源。