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静电除尘器灰“Zolest-Bet”和硅灰对波特兰水泥抗硫酸盐性的影响

Influence of Electrostatic Precipitator Ash "Zolest-Bet" and Silica Fume on Sulfate Resistance of Portland Cement.

作者信息

Barabanshchikov Yury, Usanova Kseniia, Akimov Stanislav, Uhanov Aleksandr, Kalachev Andrej

机构信息

Institute of Civil Engineering, Peter the Great St. Petersburg Polytechnic University, 195251 St. Petersburg, Russia.

Provcement-Vector JSC, 195251 St. Petersburg, Russia.

出版信息

Materials (Basel). 2020 Nov 1;13(21):4917. doi: 10.3390/ma13214917.

Abstract

The influence of the electrostatic precipitator ash "Zolest-bet" and silica fume on the sulfate resistance of Portland cement was studied. The evaluation criteria were the expansion, strength, density, and appearance of the samples, hardened in a 5% NaSO solution starting from 3 days of age for 192 days at a temperature of 20 °C and 148 days at 40 °C. The mixture with the silica fume additive had the minimum expansion under the NaSO action, and the mixture with the fly ash "Zolest-bet" additive had the greatest expansion. Zolest-bet ash in pure water shrank the mixture by 0.19 mm/m by the end of the hardening period, and it gave a linear expansion of 0.23 mm/m in a NaSO solution after hardening. The mixture can be considered sulfate resistant at a given value of linear expansion. Despite the greatest expansion, the compressive strength of the samples with the Zolest-bet additive was found to be the highest at hardening in both environments. The flexural strength was found to be the highest after being in NaSO solution. The sulfate resistance of the mixture with silica fume was higher than that of the mixture based on sulfate-resistant cement. This mixture did not have expansion in comparison with the initial length, instead it shrank, while the expansion of sulfate-resistant cement was 0.006% over the control period. The compressive strength of the mixture with the silica fume additive was slightly inferior to the strength of the mixture with Zolest-bet ash.

摘要

研究了静电除尘器灰“Zolest-bet”和硅灰对波特兰水泥抗硫酸盐性的影响。评价标准为样品在5%Na₂SO₄溶液中从3日龄开始在20℃下养护192天、在40℃下养护148天后的膨胀率、强度、密度和外观。在Na₂SO₄作用下,含硅灰添加剂的混合物膨胀最小,含粉煤灰“Zolest-bet”添加剂的混合物膨胀最大。在纯水中,Zolest-bet灰在硬化期结束时使混合物收缩0.19mm/m,硬化后在Na₂SO₄溶液中产生0.23mm/m的线性膨胀。在给定的线性膨胀值下,该混合物可被认为具有抗硫酸盐性。尽管膨胀最大,但在两种环境下硬化时,含Zolest-bet添加剂的样品抗压强度最高。抗弯强度在置于Na₂SO₄溶液后最高。含硅灰混合物的抗硫酸盐性高于基于抗硫酸盐水泥的混合物。与初始长度相比,该混合物没有膨胀,反而收缩,而抗硫酸盐水泥在对照期内的膨胀率为0.006%。含硅灰添加剂混合物的抗压强度略低于含Zolest-bet灰混合物的强度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9bdb/7663091/a7e601f01b78/materials-13-04917-g001.jpg

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