微波辅助合成新型六氮杂三亚苯树枝状支架及其性能研究。

Microwave-Assisted Synthesis and Properties of Novel Hexaazatrinaphthylene Dendritic Scaffolds.

机构信息

Departamento de Ciencias, Colegio Hispano Inglés, S.A. Rambla de Santa Cruz, 94. 38004 S/C Tenerife, Spain.

Departamento de Química Orgánica, Universidad de Cordoba, Campus de Rabanales, Edificio Marie Curie (C-3) Ctra Nnal IV-A, Km. 396 E-14014 Cordoba, Spain.

出版信息

Molecules. 2020 Oct 30;25(21):5038. doi: 10.3390/molecules25215038.

DOI:10.3390/molecules25215038

PMID:33142979

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7663666/

Abstract

A novel family of water-soluble π-conjugated hexaazatrinaphthylenes-based dendritic architectures constructed by hexaketocyclohexane and 1,2,4,5-benzenetetramine units is developed in a microwave-assisted organic synthesis (MAOS) approach. The structures and purity of these compounds are verified by H and C-NMR, MALDI-TOF MS, UV-vis, elemental analysis, DSC, AFM, STM and cyclic voltammetry.

摘要

一种新型的水溶性π共轭六氮杂三亚苯基树枝状大分子结构，由六环已酮和 1,2,4,5-苯四胺单元构建，通过微波辅助有机合成（MAOS）方法得到。通过 1H-NMR、13C-NMR、MALDI-TOF MS、UV-vis、元素分析、DSC、AFM、STM 和循环伏安法验证了这些化合物的结构和纯度。