Pristine and modified chitosan as solid catalysts for catalysis and biodiesel production: A minireview.

Chitosan is one of the readily available polymers with relatively high abundance, biodegradable and sustainable materials with divergent functional groups that are employed in broad range of applications. Chitosan is widely used in many fields like adsorption, drug carrier for therapeutic activity, environmental remediation, drug formulation and among others. One of the unique features of chitosan is that it can be transformed to other forms like beads, films, flakes, sponges and fibres depending upon the applications. This review is aimed at showing the potential applications of chitosan and its modified solids in organic transformations. The number of existing articles is organized based on the nature of materials and subsequently with the types of reactions. After a brief description on the structural features of chitosan, properties, characterization methods including various analytical/microscopic techniques and some of the best practices to be followed in catalysis are also discussed. The next section of this review describes the catalytic activity of native chitosan without any modifications while the subsequent sections provide the catalytic activity of chitosan derivatives, chitosan covalently modified with metal complexes/salts through linkers and chitosan as support for metal nanoparticles (NPs). These sections discuss number of organic reactions that include Knoevenagel condensation, oxidation, reduction, heterocycles synthesis, cross-coupling reactions and pollutant degradation among others. A separate section provides the catalytic applications of chitosan and its modified forms for the production of fatty acid methyl esters (FAME) through esterification/transesterification reactions. The final section summarizes our views on the future directions of this field in the coming years.