Department of Chemistry, Ulsan National Institute of Science and Technology, UNIST-gil 50, Ulsan 44919, Republic of Korea.
Chem Soc Rev. 2021 Jan 7;50(1):528-555. doi: 10.1039/d0cs00443j. Epub 2020 Nov 9.
Metal-organic polyhedra are a member of metal-organic materials, and are together with metal-organic frameworks utilized as emerging porous platforms for numerous applications in energy- and bio-related sciences. However, metal-organic polyhedra have been significantly underexplored, unlike their metal-organic framework counterparts. In this review, we will cover the topologies and the classification of metal-organic polyhedra and share several suggestions, which might be useful to synthetic chemists regarding the future directions in this rapid-growing field.
金属有机多面体是金属有机材料的一个成员，与金属有机骨架一起，被用作能源和生物相关科学中许多应用的新兴多孔平台。然而，与金属有机骨架相比，金属有机多面体的研究还远远不够。在这篇综述中，我们将介绍金属有机多面体的拓扑结构和分类，并分享一些建议，这些建议可能对合成化学家在这个快速发展的领域的未来方向有用。
