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木质素含量对环氧树脂浸渍制备的柔性透明杨树单板性能的影响

Effect of Lignin Content on Properties of Flexible Transparent Poplar Veneer Fabricated by Impregnation with Epoxy Resin.

作者信息

Lu Mengting, He Wen, Li Ze, Qiang Han, Cao Jizhou, Guo Feiyu, Wang Rui, Guo Zhihao

机构信息

College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China.

Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Foresry University, Nanjing 210037, China.

出版信息

Polymers (Basel). 2020 Nov 5;12(11):2602. doi: 10.3390/polym12112602.

Abstract

In this work, poplar veneer (PV) rotary-cut from fast-growing polar was delignified to prepare flexible transparent poplar veneer (TPV). Lignin was gradually removed from the PV and then epoxy resin filled into the delignified PV. The study mainly concerns the effect of lignin content on microstructure, light transmittance, haze, tensile strength, and thermal stability of the PVs impregnated with epoxy resin. The results indicate that the lignin could be removed completely from the PV when the delignification time was around 8 h, which was proved by FTIR spectra and chemical component detection. Moreover, according to SEM observation and XRD testing, the porosity and crystallinity of the PVs were gradually increased with the removal of lignin. Also, the optical properties measurement indicated that the light transmittance and haze of the TPVs gradually increased, and the thermal stability also became more stable as shown by thermogravimetric analysis (TG). However, the tensile strength of the TPVs declined due to the removal of lignin. Among them, TPV exhibited excellent optical properties, thermal stability, and tensile strength. Consequently, it has great potential to be used as a substrate in photovoltaics, solar cells, smart windows, etc.

摘要

在这项工作中,将从速生杨树旋切得到的杨树单板(PV)进行脱木质素处理,以制备柔性透明杨树单板(TPV)。木质素从PV中逐渐去除,然后将环氧树脂填充到脱木质素的PV中。该研究主要关注木质素含量对浸渍环氧树脂的PV的微观结构、透光率、雾度、拉伸强度和热稳定性的影响。结果表明,当脱木质素时间约为8小时时,PV中的木质素可被完全去除,这通过傅里叶变换红外光谱(FTIR)和化学成分检测得到证实。此外,根据扫描电子显微镜(SEM)观察和X射线衍射(XRD)测试,随着木质素的去除,PV的孔隙率和结晶度逐渐增加。而且,光学性能测量表明,TPV的透光率和雾度逐渐增加,热重分析(TG)显示其热稳定性也变得更稳定。然而,由于木质素的去除,TPV的拉伸强度下降。其中,TPV表现出优异的光学性能、热稳定性和拉伸强度。因此,它在光伏、太阳能电池、智能窗户等领域作为基材具有巨大的应用潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2fa/7694516/57a3007d4f48/polymers-12-02602-g001.jpg

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