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用一种新型的由椰枣核制备的活性炭从水中去除有机氯农药。

Elimination of organochlorine pesticides from water by a new activated carbon prepared from Phoenix dactylifera date stones.

机构信息

Université Libanaise, Faculté de santé publique section III, Laboratoire des Sciences de l'Eau et de l'Environnement (L.S.E.E), Tripoli, Lebanon.

Université de Lille, Equipe Physico-Chimie de l'Environnement, LASIR UMR CNRS 8516, Bâtiment C8, 59655, Villeneuve d'Ascq Cedex, France.

出版信息

Environ Sci Pollut Res Int. 2021 Feb;28(8):10140-10154. doi: 10.1007/s11356-020-11445-0. Epub 2020 Nov 9.

Abstract

This work focused on the characterization of activated carbon (AC) prepared by pyrolysis-chemical activation with phosphoric acid (60%) from date stones derived from three categories of date palm Phoenix dactylifera (Ajwa, Anbari, Khudri), and on its feasibility of elimination of organochlorine pesticides (OCPs) in water samples. The obtained results showed that the three-produced AC date stone had developed a porous structure, large specific surface area, and acidic property. Due to the high SBET (> 1200 m/g), Ajwa stones activated coal was considered as the best AC that can be used for the adsorption of environmental contaminants. The effects of several parameters such as the Ajwa AC dose, the time of contact, the initial concentration of pesticides, and the pH were evaluated. The results showed that the adsorption balance of organochlorine pesticides on this AC was reached after a contact time of 60 min at an optimal pHzpc equal to 2. In addition, 0.4 g of AC was the best quantity found to retain the largest quantity of pesticides while considering the economic part.

摘要

这项工作专注于从三种不同的海枣(Ajwa、Anbari、Khudri)中提取的椰枣石用 60%磷酸热解化学活化法制备的活性炭(AC)的特性及其在水样中去除有机氯农药(OCPs)的可行性研究。结果表明,三种椰枣石制备的活性炭具有发达的多孔结构、大的比表面积和酸性。由于高比表面积(>1200 m/g),Ajwa 椰枣石活性炭被认为是最好的 AC,可用于吸附环境污染物。考察了 Ajwa AC 剂量、接触时间、农药初始浓度和 pH 值等多个参数的影响。结果表明,在最佳 pH 值 pHzpc 等于 2 时,有机氯农药在该 AC 上的吸附平衡在 60 min 的接触时间后达到。此外,考虑到经济性,0.4 g 的 AC 是发现的最佳量,可保留最大量的农药。

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