Wei Duo, Darcel Christophe
Univ Rennes, CNRS, ISCR - UMR 6226, F-35000 Rennes, France.
J Org Chem. 2020 Nov 20;85(22):14298-14306. doi: 10.1021/acs.joc.0c01637. Epub 2020 Nov 10.
The last decades have seen an impressive development of iron complexes involving organophosphorus ligands applied in homogeneous catalyzed hydrometalation of olefins and alkynes. Two main topics will be covered in this JOCSynopsis: (i) an overview of the achievements in the area of iron-catalyzed hydrophosphination and then (ii) hydrosilylation, hydroborylation, and hydromagnesiation reactions promoted by catalysts based on organophosphorus ligands and iron.
在过去几十年中，涉及有机磷配体的铁配合物在烯烃和炔烃的均相催化氢金属化反应中取得了令人瞩目的进展。本《有机化学杂志》综述将涵盖两个主要主题：（i）铁催化氢磷化领域的成就概述，以及（ii）基于有机磷配体和铁的催化剂促进的硅氢化、硼氢化和镁氢化反应。
