Department of Chemical and Biomolecular Engineering, Ohio University, Athens, OH, 45701, USA.
Biorefining Research Institute, Lakehead University, Thunder Bay, ON, Canada.
Appl Biochem Biotechnol. 2021 Mar;193(3):791-806. doi: 10.1007/s12010-020-03452-1. Epub 2020 Nov 13.
In this study, we present a techno-economic analysis for integrating an electrochemical reactor into a lignocellulosic biorefinery for the purpose of converting biorefinery lignin to higher-value industrial chemicals with co-generation of hydrogen. We consider how the electrochemical reactor impacts the manufacturing costs for producing biofuel and determine a break-even value for the lignin oxidation product stream, which is the minimum lignin conversion product stream value that renders the cost to produce biofuel the same as in the typical biorefinery concept. We conclude that at low extents of lignin conversion, the break-even product stream value is likely too high for the process to be feasible. However, at higher extents of lignin conversion, the break-even product stream value may be between $1.00 and $2.00/kg, depending on capital cost and other manufacturing costs like depreciation. Potential markets for the biomass conversion products include resin manufacturing, where the products would compete with petroleum-derived resin precursors.
在这项研究中,我们提出了一项技术经济分析,旨在将电化学反应器集成到木质纤维素生物炼制厂中,以将生物炼制厂木质素转化为更有价值的工业化学品,并同时联产氢气。我们考虑了电化学反应器对生产生物燃料的制造成本的影响,并确定了木质素氧化产物流的盈亏平衡点价值,即木质素转化率产物流的最低价值,使得生产生物燃料的成本与典型生物炼制厂概念相同。我们的结论是,在木质素转化率较低的情况下,盈亏平衡点产物流的价值可能过高,使得该过程不可行。然而,在更高的木质素转化率下,盈亏平衡点产物流的价值可能在 1.00 美元至 2.00 美元/千克之间,具体取决于资本成本和其他制造成本,如折旧。生物质转化产品的潜在市场包括树脂制造,其中产品将与石油衍生的树脂前体竞争。