Electrodeposition of NiSe/MoSe as a bifunctional electrocatalyst towards highly-efficient overall water splitting.

Electrochemically splitting water into hydrogen and oxygen plays a significant role in the commercialization of hydrogen energy as well as fuel cells, but it remains a challenge to design and fabricate low-cost and high-efficiency electrocatalysts. Herein, we successfully prepared Ni3Se2/MoSex on nickel foam via a facile electrodeposition method. To understand the electrochemical mechanism occurring in the electrodeposition process, a new model was proposed, providing insight into the nucleation and growth of deposited materials. The as-prepared Ni3Se2/MoSex exhibits splendid electrochemical performance with 82 mV and 270 mV overpotentials to drive a current density of 10 mA cm-2 in 1 M KOH aqueous solution for HER and OER, respectively. Moreover, a driving potential of 1.57 V is required to reach a current density of 10 mA cm-2 for a configured full cell with Ni3Se2/MoSex working as both the anode and cathode towards overall water splitting, outperforming the state-of-the-art commercial full cells assembled with noble-based metals. The advanced catalytic performance should be attributed to the numerous in situ formed interfaces, allowing π-electron transfer from Ni to Mo via O2- bridging, subsequently optimizing the adsorption features of oxygenated species (OER) and favorable Volmer/Heyrovsky reaction (HER). This work offers an effective and scalable fabrication prototype for the preparation of bifunctional electrocatalysts with electrodeposition.