一维碘化铋（III）-碘铋酸盐杂化物Cat{[BiI](I)}：合成、稳定性及光学性质
One-Dimensional Diiodine-Iodobismuthate(III) Hybrids Cat{[BiI](I)}: Syntheses, Stability, and Optical Properties.
作者信息
Usoltsev Andrey N, Korobeynikov Nikita A, Novikov Alexander S, Plyusnin Pavel E, Kolesov Boris A, Fedin Vladimir P, Sokolov Maxim N, Adonin Sergey A
机构信息
Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences (SB RAS), Lavrentieva Street, Novosibirsk 630090, Russia.
Novosibirsk State University, Pirogova Street 2, Novosibirsk 630090, Russia.
出版信息
Inorg Chem. 2020 Dec 7;59(23):17320-17325. doi: 10.1021/acs.inorgchem.0c02599. Epub 2020 Nov 17.
One-dimensional iodine-rich iodobismuthates(III), Cat{BiI} [Cat = 1,4-MePy () and 1-EtBMAP ()], feature the highest amount of "trapped" diiodine units in polyhalogen-halometalates of p-block elements. Both complexes have narrow optical band gaps (1.55 and 1.63 eV, respectively) and moderate thermal stability.
一维富碘碘铋酸盐（III），Cat{BiI} [Cat = 1,4-甲基吡啶（ ）和1-乙基苄基甲基铵（ ）]，在p区元素的多卤化物-卤金属酸盐中具有最高数量的“捕获”双碘单元。两种配合物都具有窄的光学带隙（分别为1.55和1.63 eV）和适度的热稳定性。
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