Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia.
Molecules. 2022 Jun 16;27(12):3859. doi: 10.3390/molecules27123859.
Three supramolecular bromostannates(IV) with "trapped" diiodine molecules, Cat{SnBr} (Cat = MeN (), 1-MePy () and 4-MePyH ()), were synthesized. In all cases, I linkers are connected with bromide ligands via halogen···halogen non-covalent interactions. Articles were studied using Raman spectroscopy, thermogravimetric analysis, and diffuse reflectance spectroscopy. The latter indicates that are narrow band gap semiconductors.
三种具有“捕获”二碘分子的超分子溴锡酸盐（IV），Cat{SnBr}（Cat = MeN ()，1-MePy () 和 4-MePyH ()）被合成出来。在所有情况下，碘连接物都通过卤素···卤素非共价相互作用与溴化物配体相连。使用拉曼光谱、热重分析和漫反射光谱对 Articles 进行了研究。后者表明 是窄带隙半导体。
