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一种基于 Eu 基 MOF 的多功能逻辑探测器和荧光膜,用于快速检测溶液和气相中的甲醛。

A versatile logic detector and fluorescent film based on Eu-based MOF for swift detection of formaldehyde in solutions and gas phase.

机构信息

Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China.

Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China.

出版信息

J Hazard Mater. 2021 May 15;410:124624. doi: 10.1016/j.jhazmat.2020.124624. Epub 2020 Nov 19.

Abstract

Due to the huge threat of formaldehyde (FA) on human beings, the development of chemical sensors for swift detection of FA in solutions and gas phase is highly anticipated. In this paper, a versatile logic detector and a portable fluorescent film based on small-scaled Eu-based MOF were applied successfully to detect FA in solutions and gas phase, respectively. For FA in aqueous solution, the design of logic detector will efficiently identify FA in different concentration ranges: when the FA concentration are 0-500 ppb, 500-1000 ppb and >1000 ppb, the output signals of logic detector are the concentration level of FA ("L", "H" and "VH"), and accompanied by red, purple and blue signal lamps to remind, respectively. For FA in the air, the color of rigid film sensor will gradually change from red to blue with the increase of FA under UV lamp, and the detection limit of gaseous FA is 11.8 ppb. Through the preparation of logic devices and fluorescent films, Eu-based MOF realized swift detection of FA in solutions and gas phase, which will be very helpful to improve the human response level to FA from different emission sources.

摘要

由于甲醛(FA)对人类的巨大威胁,人们高度期待开发用于快速检测溶液和气相中 FA 的化学传感器。在本文中,一种多功能逻辑探测器和一种基于小规模 Eu 基 MOF 的便携式荧光膜分别成功应用于检测溶液和气相中的 FA。对于水溶液中的 FA,逻辑探测器的设计可有效地识别不同浓度范围的 FA:当 FA 浓度分别为 0-500 ppb、500-1000 ppb 和>1000 ppb 时,逻辑探测器的输出信号为 FA 的浓度水平(“L”、“H”和“VH”),并伴有红色、紫色和蓝色信号灯提醒,分别。对于空气中的 FA,在紫外灯下,刚性膜传感器的颜色会随着 FA 的增加而逐渐从红色变为蓝色,气态 FA 的检测限为 11.8 ppb。通过逻辑器件和荧光膜的制备,Eu 基 MOF 实现了对溶液和气相中 FA 的快速检测,这将有助于提高人类对不同来源 FA 的反应水平。

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