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卟啉在氧化物表面的电荷促进自金属化作用

Charge-Promoted Self-Metalation of Porphyrins on an Oxide Surface.

作者信息

Egger Larissa, Hollerer Michael, Kern Christian S, Herrmann Hannes, Hurdax Philipp, Haags Anja, Yang Xiaosheng, Gottwald Alexander, Richter Mathias, Soubatch Serguei, Tautz F Stefan, Koller Georg, Puschnig Peter, Ramsey Michael G, Sterrer Martin

机构信息

Institute of Physics, NAWI Graz, University of Graz, Universitätsplatz 5, 8010, Graz, Austria.

Peter Grünberg Institute (PGI-3), Forschungszentrum Jülich, 52425, Jülich, Germany.

出版信息

Angew Chem Int Ed Engl. 2021 Mar 1;60(10):5078-5082. doi: 10.1002/anie.202015187. Epub 2021 Jan 14.

DOI:10.1002/anie.202015187
PMID:33245197
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7986846/
Abstract

Metalation and self-metalation reactions of porphyrins on oxide surfaces have recently gained interest. The mechanism of porphyrin self-metalation on oxides is, however, far from being understood. Herein, we show by a combination of results obtained with scanning tunneling microscopy, photoemission spectroscopy, and DFT computations, that the self-metalation of 2H-tetraphenylporphyrin on the surface of ultrathin MgO(001) films is promoted by charge transfer. By tuning the work function of the MgO(001)/Ag(001) substrate, we are able to control the charge and the metalation state of the porphyrin molecules on the surface.

摘要

卟啉在氧化物表面的金属化和自金属化反应近来备受关注。然而，卟啉在氧化物上的自金属化机理仍远未明晰。在此，我们通过扫描隧道显微镜、光电子能谱和密度泛函理论计算相结合的结果表明，电荷转移促进了2H-四苯基卟啉在超薄MgO(001)薄膜表面的自金属化。通过调节MgO(001)/Ag(001)衬底的功函数，我们能够控制表面卟啉分子的电荷和金属化状态。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/124d/7986846/3ae8ab4ce2a5/ANIE-60-5078-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/124d/7986846/524bee682c44/ANIE-60-5078-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/124d/7986846/63df20d8f983/ANIE-60-5078-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/124d/7986846/b132b2b4609a/ANIE-60-5078-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/124d/7986846/3ae8ab4ce2a5/ANIE-60-5078-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/124d/7986846/524bee682c44/ANIE-60-5078-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/124d/7986846/63df20d8f983/ANIE-60-5078-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/124d/7986846/b132b2b4609a/ANIE-60-5078-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/124d/7986846/3ae8ab4ce2a5/ANIE-60-5078-g002.jpg

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本文引用的文献

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Controlling the electronic and physical coupling on dielectric thin films.控制介电薄膜上的电子和物理耦合。
Beilstein J Nanotechnol. 2020 Oct 1;11:1492-1503. doi: 10.3762/bjnano.11.132. eCollection 2020.
2
Interfacial Reactions of Tetraphenylporphyrin with Cobalt-Oxide Thin Films.四苯基卟啉与氧化钴薄膜的界面反应。
Chemistry. 2019 Oct 11;25(57):13197-13201. doi: 10.1002/chem.201902680. Epub 2019 Sep 13.
3
Multi-orbital charge transfer at highly oriented organic/metal interfaces.高度取向有机/金属界面的多轨道电荷转移。
卟啉在超薄MgO(001)薄膜上的自金属化作用对电荷和吸附高度的依赖性
Phys Chem Chem Phys. 2022 Nov 30;24(46):28540-28547. doi: 10.1039/d2cp04688a.
4
Self-Metalation of Porphyrins at the Solid-Gas Interface.卟啉在固-气界面的自金属化作用。
Angew Chem Int Ed Engl. 2021 Dec 1;60(49):25988-25993. doi: 10.1002/anie.202111932. Epub 2021 Nov 9.
5
Demonstrating the Impact of the Adsorbate Orientation on the Charge Transfer at Organic-Metal Interfaces.展示吸附质取向对有机-金属界面电荷转移的影响。
J Phys Chem C Nanomater Interfaces. 2021 May 6;125(17):9129-9137. doi: 10.1021/acs.jpcc.1c01306. Epub 2021 Apr 27.
Nat Commun. 2017 Aug 25;8(1):335. doi: 10.1038/s41467-017-00402-0.
4
Very high temperature tiling of tetraphenylporphyrin on rutile TiO(110).锐钛矿 TiO(110)表面上的四苯基卟啉的高温平铺。
Nanoscale. 2017 Aug 17;9(32):11694-11704. doi: 10.1039/c7nr04093h.
5
Charge Transfer and Orbital Level Alignment at Inorganic/Organic Interfaces: The Role of Dielectric Interlayers.无机/有机界面的电荷转移和轨道能级排列：介电层的作用。
ACS Nano. 2017 Jun 27;11(6):6252-6260. doi: 10.1021/acsnano.7b02449. Epub 2017 May 31.
6
Interaction of free-base tetraphenylporphyrin with magnesium oxide: Influence of MgO morphology on metalation.游离碱四苯基卟啉与氧化镁的相互作用：氧化镁形态对金属化的影响。
J Chem Phys. 2017 Feb 14;146(6):064702. doi: 10.1063/1.4975229.
7
In vacuo interfacial tetrapyrrole metallation.真空界面四吡咯金属化。
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Porphyrin Metalation at MgO Surfaces: A Spectroscopic and Quantum Mechanical Study on Complementary Model Systems.氧化镁表面的卟啉金属化：互补模型体系的光谱和量子力学研究
Chemistry. 2016 Jan 26;22(5):1744-9. doi: 10.1002/chem.201503661. Epub 2015 Dec 18.
9
Porphyrin Metalation at the MgO Nanocube/Toluene Interface.氧化镁纳米立方体/甲苯界面处的卟啉金属化
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