College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China.
Department of Agronomy, School of Life Sciences, Inner Mongolia University, Hohhot 010020, China.
Molecules. 2020 Nov 26;25(23):5541. doi: 10.3390/molecules25235541.
Lavender and its products have excellent flavor properties. However, most studies focus on the aroma profiles of lavender essential oil (LEO). The volatiles in lavender extracts (LEs), either in volatile compositions or their odor characteristics, have rarely been reported. In this study, the odor characteristics of LEs and LEO were comprehensively investigated by gas chromatography-mass spectrometry (GC-MS), coupled with sensory evaluation and principal chemical analysis (PCA). In addition, the extraction conditions of lavender extracts from inflorescences of Mill. were optimized. Under the optimal conditions of extraction, twice with 95% edible ethanol as the solvent, the LEs tended to contain the higher intensity of characteristic floral, herbal and clove-like odors as well as higher scores of overall assessment and higher amounts of linalool, linalool oxides I and II, linalyl acetate, lavandulyl acetate and total volatiles than LEO. PCA analysis showed that there were significant differences on the odor characteristics between LEO and LEs. The LEO, which was produced by steam distillation with a yield of 2.21%, had the lower intensity of floral, clove-like, medicine-like, pine-like and hay notes, a lower score of overall assessment and lower levels of linalool oxides I and II, linalyl acetate, lavandulyl acetate and total volatiles compared with LEs, whereas the relative contents of linalool and camphor in LEO were significantly higher than that in LEs. Furthermore, the earthy, green and watery odors were only found in LEO. Concerning the odor characteristics and volatile compositions, the LEs had better odor properties than LEO. These results provided a theoretical basis for the industrial preparation of lavender-related products.
薰衣草及其产品具有优良的风味特性。然而,大多数研究都集中在薰衣草精油(LEO)的香气特征上。薰衣草提取物(LEs)中的挥发性成分,无论是在挥发性成分组成还是气味特征方面,都很少有报道。在这项研究中,通过气相色谱-质谱联用(GC-MS),结合感官评价和主成分分析(PCA),全面研究了 LEs 和 LEO 的气味特征。此外,还优化了从薰衣草花序中提取薰衣草提取物的条件。在提取条件最佳的情况下,用 95%食用乙醇作为溶剂提取两次,LEs 往往具有更高的特征花香、草药香和丁香香强度,以及更高的整体评价得分和更高的芳樟醇、芳樟醇氧化物 I 和 II、乙酸芳樟酯、乙酸薰衣草酯和总挥发物含量,而 LEO 则不然。PCA 分析表明,LEO 和 LEs 在气味特征上存在显著差异。LEO 是通过水蒸气蒸馏法以 2.21%的收率制备的,其花香、丁香香、药香、松木香和干草香强度较低,整体评价得分较低,芳樟醇氧化物 I 和 II、乙酸芳樟酯、乙酸薰衣草酯和总挥发物水平较低,而 LEO 中的芳樟醇和樟脑的相对含量明显高于 LEs。此外,泥土、绿色和水样气味仅在 LEO 中发现。就气味特征和挥发性成分而言,LEs 的气味特性优于 LEO。这些结果为薰衣草相关产品的工业制备提供了理论依据。