Department of Chemistry, Ho Chi Minh City University of Education, 280 An Duong Vuong Street, District 5, Ho Chi Minh City 748342, Vietnam.
Laboratory of Computational Chemistry and Modelling (LCCM), Quy Nhon University, Bình Định 55100, Vietnam.
J Asian Nat Prod Res. 2021 Nov;23(11):1093-1099. doi: 10.1080/10286020.2020.1844189. Epub 2020 Dec 1.
A novel dimeric alkylresorcinol derivative, manilkzapotane (), along with seven known compounds, lupeol acetate (), lupeol (), arjunolic acid (), ergosterol peroxide (), taraxerol (), hederagonic acid (), and glochidiol () were isolated from the stem bark of . Their structures were determined on the basis of spectroscopic data. DFT-NMR chemical shift calculations and a modified probability (DP4+) method were applied to define the relative configuration of . To the best of our knowledge, this represents the first isolation of a dimeric alkylresorcinol derivative from the Sapotaceae family.
从瓜栗的茎皮中分离得到一个新的二聚烷基间苯二酚衍生物马尼尔卡波坦(),以及另外七个已知化合物:乙酸羽扇醇酯()、羽扇醇()、乌苏酸()、麦角甾烷过氧化物()、蒲公英甾醇()、hederagonic 酸()和 glochidiol ()。基于光谱数据确定了它们的结构。应用 DFT-NMR 化学位移计算和改进的概率(DP4+)方法确定了的相对构型。据我们所知,这是首次从山榄科中分离出二聚烷基间苯二酚衍生物。