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固液界面的热力学

Thermodynamics at Solid-Liquid Interfaces.

作者信息

Frank Michael, Drikakis Dimitris

机构信息

Department of Mechanical Aerospace and Engineering, University of Strathclyde, 75 Montrose, Glasgow G11UX, UK.

出版信息

Entropy (Basel). 2018 May 12;20(5):362. doi: 10.3390/e20050362.

Abstract

The variation of the liquid properties in the vicinity of a solid surface complicates the description of heat transfer along solid-liquid interfaces. Using Molecular Dynamics simulations, this investigation aims to understand how the material properties, particularly the strength of the solid-liquid interaction, affect the thermal conductivity of the liquid at the interface. The molecular model consists of liquid argon confined by two parallel, smooth, solid walls, separated by a distance of 6.58 . We find that the component of the thermal conductivity parallel to the surface increases with the affinity of the solid and liquid.

摘要

固体表面附近液体性质的变化使沿固液界面的传热描述变得复杂。本研究采用分子动力学模拟,旨在了解材料性质,特别是固液相互作用强度如何影响界面处液体的热导率。分子模型由被两个平行、光滑的固体壁限制的液态氩组成,两壁间距为6.58 。我们发现,热导率平行于表面的分量随固体与液体的亲和性增加而增大。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12e7/7512882/e5050f50549c/entropy-20-00362-g001.jpg

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