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电镀污泥的处理、再利用、浸出特性及遗传毒性评价。

Treatment, reuse, leaching characteristics and genotoxicity evaluation of electroplating sludge.

机构信息

Departamento de Engenharia, Escola de Engenharia, Universidade Federal de Lavras, Lavras, Brazil.

Departmento de Química, Instituto de Ciências Naturais, Universidade Federal de Lavras, Lavras, Brazil.

出版信息

J Environ Manage. 2021 Feb 15;280:111706. doi: 10.1016/j.jenvman.2020.111706. Epub 2020 Dec 1.

Abstract

Electroplating sludge (ES) is a waste that is generated by the galvanization industry and is highly toxic because it contains heavy metals. This study examined the physiochemical properties of ES residue, the recovery of the present metals, and the reuse of these metals to add value to this residue and avoid environmental contamination through its inadequate disposal. The potential for leaching of ES was investigated using various tests, and a decrease in the germination speed of Lactuca sativa seeds and the appearance of chromosomal aberrations in the cytotoxicity tests were observed. The reduction of the pH and dynamic leaching conditions favor the leaching of ES heavy metals. An increase in the ES concentration in soil decreases the speed of germination and increases the number of chromosomal aberrations that are related to aneugenic phenomena that promote tumor development. Metals were recovered through solubilization, followed by selective precipitation. The recovery of heavy metals from ES decreased its toxicity by eliminating toxic components. The reuse of the metals in the electroplating process may reduce the cost of disposal of ES, thereby rendering it an economically and environmentally friendly alternative. The products that were galvanized using the recovered solution showed the best results in the corrosion test, thereby demonstrating the viability of the use of this solution in industrial galvanization.

摘要

电镀污泥(ES)是一种由镀锌行业产生的高毒性废物,因为它含有重金属。本研究考察了 ES 残渣的物理化学性质、现有金属的回收以及这些金属的再利用,以增加残渣的附加值,并通过妥善处理避免环境受到污染。通过各种试验研究了 ES 的浸出潜力,观察到在发芽速度测试中莴苣种子发芽速度降低,在细胞毒性测试中出现染色体异常。降低 pH 值和动态浸出条件有利于 ES 重金属的浸出。土壤中 ES 浓度的增加会降低发芽速度,并增加与促进肿瘤发展的非整倍体现象相关的染色体异常数量。通过溶解随后选择性沉淀来回收重金属。从 ES 中回收重金属可以通过消除有毒成分来降低其毒性。在电镀过程中重新使用这些金属可以降低 ES 处置的成本,从而使其成为一种经济和环保的选择。使用回收溶液镀锌的产品在腐蚀测试中表现出最佳效果,从而证明了在工业镀锌中使用该溶液的可行性。

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