Chien Chia-Chen, Kao Shih-Chieh, Chen Chun-Jen, Wu Yen-Ku
Department of Applied Chemistry, National Chiao Tung University, 1001 University Road, Hsinchu 30010, Taiwan.
Chem Commun (Camb). 2020 Dec 21;56(98):15470-15472. doi: 10.1039/d0cc07331h. Epub 2020 Dec 7.
A flow edition of photo-Fries rearrangement for the synthesis of 2-acylphenols in an aqueous micellar medium has been described. We take advantage of a narrow channel reactor and micelle-induced confinement effect to refine both the efficiency and selectivity of the parent photoreaction.
描述了一种在水性胶束介质中合成2-酰基苯酚的光-Fries重排流动版方法。我们利用窄通道反应器和胶束诱导的限域效应来提高母体光反应的效率和选择性。
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