Pérez Nicolás, Wolf Constantin, Kunzmann Alexander, Freudenberger Jens, Krautz Maria, Weise Bruno, Nielsch Kornelius, Schierning Gabi
Institute for Metallic Materials, IFW-Dresden, 01069 Dresden, Germany.
Institute of Materials Science, TU Dresden, 01062 Dresden, Germany.
Entropy (Basel). 2020 Feb 21;22(2):244. doi: 10.3390/e22020244.
The entropy of conduction electrons was evaluated utilizing the thermodynamic definition of the Seebeck coefficient as a tool. This analysis was applied to two different kinds of scientific questions that can-if at all-be only partially addressed by other methods. These are the field-dependence of meta-magnetic phase transitions and the electronic structure in strongly disordered materials, such as alloys. We showed that the electronic entropy change in meta-magnetic transitions is not constant with the applied magnetic field, as is usually assumed. Furthermore, we traced the evolution of the electronic entropy with respect to the chemical composition of an alloy series. Insights about the strength and kind of interactions appearing in the exemplary materials can be identified in the experiments.
利用塞贝克系数的热力学定义作为工具来评估传导电子的熵。该分析应用于两类不同的科学问题,这些问题即便能用其他方法解决,也只能部分解决。这两类问题是亚磁相变的场依赖性以及强无序材料(如合金)中的电子结构。我们表明,亚磁相变中的电子熵变并不像通常所假设的那样随外加磁场保持恒定。此外,我们追踪了合金系列中电子熵随化学成分的演变。在实验中可以确定有关示例材料中出现的相互作用强度和类型的见解。