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源自喹吖啶酮的二氮杂并五苯

Diazapentacenes from Quinacridones.

作者信息

Wiesner Thomas, Ahrens Lukas, Rominger Frank, Freudenberg Jan, Bunz Uwe H F

机构信息

Organisch Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.

出版信息

Chemistry. 2021 Mar 8;27(14):4553-4556. doi: 10.1002/chem.202004761. Epub 2021 Feb 17.

DOI:10.1002/chem.202004761
PMID:33289942
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7986698/
Abstract

Bis(silylethynylated) 5,7- and 5,12-diazapentacenes were synthesized from cis- and trans-quinacridone using protection, alkynylation and deoxygenation. The solid-state packing of the targets is determined by choice and position of the silylethynyl substituents. The position of the substituents and nitrogen atoms influence the optical properties of the targets.

摘要

通过保护、炔基化和脱氧反应，由顺式和反式喹吖啶酮合成了双（硅乙炔基）化的5,7-二氮杂并五苯和5,12-二氮杂并五苯。目标化合物的固态堆积由硅乙炔基取代基的选择和位置决定。取代基和氮原子的位置影响目标化合物的光学性质。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/fc6c6e92e629/CHEM-27-4553-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/aac61b302416/CHEM-27-4553-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/542721de1664/CHEM-27-4553-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/2857ccfa1d5c/CHEM-27-4553-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/99b1c6c0d8a8/CHEM-27-4553-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/fc6c6e92e629/CHEM-27-4553-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/aac61b302416/CHEM-27-4553-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/542721de1664/CHEM-27-4553-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/2857ccfa1d5c/CHEM-27-4553-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/99b1c6c0d8a8/CHEM-27-4553-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf41/7986698/fc6c6e92e629/CHEM-27-4553-g001.jpg

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