Castillo-Blas Celia, Romero-Muñiz Ignacio, Mavrandonakis Andreas, Simonelli Laura, Platero-Prats Ana E
Departamento de Química Inorgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Campus de Cantoblanco, Madrid 28049, Spain.
Chem Commun (Camb). 2020 Dec 21;56(100):15615-15618. doi: 10.1039/d0cc06134d. Epub 2020 Dec 8.
Stabilizing catalytic iron-oxo-clusters within nanoporous metal-organic frameworks (MOFs) is a powerful strategy to prepare new active materials for the degradation of toxic chemicals, such as bisphenol A. Herein, we combine pair distribution function analysis of total X-ray scattering data and X-ray absorption spectroscopy, with computational modelling to understand the local structural nature of added redox-active iron-oxo clusters bridging neighbouring zirconia-nodes within MOF-808.
在纳米多孔金属有机框架（MOF）中稳定催化铁氧簇是制备用于降解有毒化学物质（如双酚A）的新型活性材料的有力策略。在此，我们将总X射线散射数据的对分布函数分析和X射线吸收光谱与计算模型相结合，以了解MOF-808中相邻氧化锆节点之间添加的氧化还原活性铁氧簇的局部结构性质。
