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利用辣木籽粉(MSSP)和香蕉皮粉(BPP)通过生物吸附法有效去除废水中的六价铬。

Bio-sorption for effective removal of chromium(VI) from wastewater using Moringa stenopetala seed powder (MSSP) and banana peel powder (BPP).

作者信息

Badessa Tolera Seda, Wakuma Esayas, Yimer Ali Mohammed

机构信息

Department of Chemistry, College of Natural Sciences, Arba Minch University, Arba Minch, Ethiopia.

出版信息

BMC Chem. 2020 Dec 10;14(1):71. doi: 10.1186/s13065-020-00724-z.

Abstract

Chromium is an extremely toxic metal in the form of Cr(VI) that causes severe environmental and health problems. Therefore, the aim of this study was to remove chromium ions from wastewater by using cost effective and environmentally friendly bio-sorbents; Moringa stenopetala seed powder (MSSP), and banana peel powder (BPP) and to evaluate its adsorption capacities as bio-sorbents. FT-IR characterization of the adsorbents showed that there was a change in the functional groups of the structure of both adsorbents before and after the adsorption that might be due to the adsorption processes taken place on the surface of adsorbent. Adsorption experiments were carried out as batch studies with different contact times, pH, adsorbent dose, initial metal ion concentration, and temperature. Results showed maximum removal efficiency for Cr(VI) at 120 min contact time, adsorbent dose of 20 g/L and pH 2 by MSSP and pH 4 by BPP. The percentage removal of Cr(VI) increased with increasing adsorbent dose (from 5 to 20 g/L) and contact time (from 60 to 120 min). Freundlich isotherm model showed a better fit to the equilibrium data than the Langmuir model. The kinetics of adsorption for chromium was well represented by pseudo-second order kinetic model and the calculated equilibrium sorption capacity of the model showed good agreement with the sorption capacity obtained from experimental results.

摘要

铬以六价铬(Cr(VI))的形式存在时是一种剧毒金属,会引发严重的环境和健康问题。因此,本研究的目的是使用具有成本效益且环保的生物吸附剂——狭叶辣木籽粉(MSSP)和香蕉皮粉(BPP)从废水中去除铬离子,并评估其作为生物吸附剂的吸附能力。吸附剂的傅里叶变换红外光谱(FT-IR)表征表明,两种吸附剂在吸附前后结构的官能团发生了变化,这可能是由于吸附过程发生在吸附剂表面。吸附实验以批次研究的方式进行,涉及不同的接触时间、pH值、吸附剂剂量、初始金属离子浓度和温度。结果表明,MSSP在接触时间为120分钟、吸附剂剂量为20 g/L且pH值为2时,对Cr(VI)的去除效率最高;BPP在pH值为4时去除效率最高。Cr(VI)的去除率随吸附剂剂量(从5 g/L增加到20 g/L)和接触时间(从60分钟增加到120分钟)的增加而提高。Freundlich等温线模型比Langmuir模型更能拟合平衡数据。铬的吸附动力学可用准二级动力学模型很好地描述,该模型计算出的平衡吸附容量与实验结果获得的吸附容量吻合良好。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7d2a/7727115/c823ce3d138b/13065_2020_724_Fig1_HTML.jpg

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