State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
Bioresour Technol. 2021 Feb;321:124505. doi: 10.1016/j.biortech.2020.124505. Epub 2020 Dec 7.
Co-gasification of coal and biomass offers a relatively cleaner utilization way of fossil fuel. The fuel property improvement of biomass can not only improve the property of syngas but also enhance the synergistic effect during the co-gasification. In our previous work, a novel gas-pressurized (abbreviated as GP) torrefaction was proposed to effectively upgrade the biomass under mild condition. In this work, the co-gasification of GP torrefied biomass and coal were conducted to explore the synergistic effect and kinetics. Significant synergistic effect during the co-gasification was proved. The CO yield of co-gasification increased to as high as 70.70 mol/kg, resulting from the promotion of carbon in coal converting into CO by GPRS. Furthermore, the kinetic model of RPM was most fitting for the co-gasification, and the activation energy of co-gasification was reduced. Thus, the coal gasification was promoted significantly by GP torrefied biomass through obvious synergistic effect during the co-gasification.
煤与生物质共气化提供了一种相对清洁的化石燃料利用方式。生物质燃料特性的改善不仅可以提高合成气的性质,还可以增强共气化过程中的协同效应。在我们之前的工作中,提出了一种新型的加压气体热解(简称 GP)方法,可在温和条件下有效地升级生物质。在这项工作中,进行了 GP 热解生物质与煤的共气化实验,以探索协同效应和动力学。共气化过程中存在显著的协同效应。由于 GPRS 将煤中的碳转化为 CO,共气化的 CO 产率高达 70.70 mol/kg。此外,RPM 动力学模型最适合共气化,共气化的活化能降低。因此,通过共气化过程中的明显协同效应,GP 热解生物质显著促进了煤气化。