Pyeon Jeongsu, Kim Hyoungsoo
Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology, Daejeon 34141, Republic of Korea.
Soft Matter. 2021 Apr 7;17(13):3578-3585. doi: 10.1039/d0sm01872d. Epub 2020 Dec 15.
Surface-coating technologies are important for a variety of applications, e.g. ink-jet printing, micro-electronic engineering and biological arrays. In this study, we introduce a novel idea to obtain uniform patterns with multi-component solution in a confined geometry. When a droplet of the multi-component liquid evaporates in the confined area, the evaporated vapors are stagnated inside the confined chamber where the evaporated liquid molecule is much heavier than the ambient air. These vapors change internal flow in the droplet by generating Marangoni effects during evaporation, which help to obtain uniform deposition. Finally, we show that a coffee-ring is totally suppressed and a uniformly dried pattern is achieved. For a potential application as display panels, we use quantum dots and create a uniform light-emitting layer.
表面涂层技术在多种应用中都很重要,例如喷墨打印、微电子工程和生物阵列。在本研究中,我们引入了一种新颖的想法,即在受限几何结构中用多组分溶液获得均匀图案。当多组分液体的液滴在受限区域内蒸发时,蒸发的蒸汽会滞留在受限腔内,在该腔内蒸发的液体分子比周围空气重得多。这些蒸汽在蒸发过程中通过产生马兰戈尼效应改变液滴内部的流动,这有助于获得均匀的沉积。最后,我们表明咖啡环被完全抑制,实现了均匀干燥的图案。对于作为显示面板的潜在应用,我们使用量子点并创建了一个均匀的发光层。