Murphy Gabriel L, Wang Yaxing, Kegler Philip, Wang Yumin, Wang Shuao, Alekseev Evgeny V
Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich 52428, Germany.
Chem Commun (Camb). 2021 Jan 14;57(4):496-499. doi: 10.1039/d0cc06835g. Epub 2020 Dec 17.
Herein we report the first example of an actinide polyiodate compound, namely K[(UO)(IO)(IO)]·(HIO)(HO) (UPI-1), which was obtained from slow evaporation of nitric acid with a high I/U ratio. Spectroscopic measurements indicate that UPI-1 possesses X-ray luminescence properties applicable for X-ray scintillation and also exhibits modest protonic conduction.
在此，我们报道了首例锕系元素多碘酸盐化合物，即K[(UO)(IO)(IO)]·(HIO)(HO)（UPI-1），它是通过高碘/铀比的硝酸缓慢蒸发得到的。光谱测量表明，UPI-1具有适用于X射线闪烁的X射线发光特性，并且还表现出适度的质子传导性。
