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基于丙烯酸酯的含木质素聚合物复合材料的可燃性测试及性能研究。

Flammability Tests and Investigations of Properties of Lignin-Containing Polymer Composites Based on Acrylates.

机构信息

Department of Polymer Chemistry, Institute of Chemical Science, Faculty of Chemistry, Maria Curie-Sklodowska University, M. Curie-Sklodowska Sq. 3, 20-031 Lublin, Poland.

Analytical Laboratory, Institute of Chemical Science, Faculty of Chemistry, Maria Curie-Sklodowska University, M. Curie-Sklodowska Sq. 3, 20-031 Lublin, Poland.

出版信息

Molecules. 2020 Dec 15;25(24):5947. doi: 10.3390/molecules25245947.

DOI:10.3390/molecules25245947
PMID:33334041
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7765523/
Abstract

In this paper flammability tests and detailed investigations of lignin-containing polymer composites' properties are presented. Composites were obtained using bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BPA.GDA), ethylene glycol dimethacrylate (EGDMA), and kraft lignin (lignin alkali, L) during UV curing. In order to evaluate the influence of lignin modification and the addition of flame retardant compounds on the thermal resistance of the obtained biocomposites, flammability tests have been conducted. After the modification with phosphoric acid (V) lignin, as well as diethyl vinylphosphonate, were used as flame retardant additives. The changes in the chemical structures (ATR-FTIR), as well as the influence of the different additives on the hardness, thermal (TG) and mechanical properties were discussed in detail. The samples after the flammability test were also studied to assess their thermal destruction.

摘要

本文介绍了含木质素聚合物复合材料的可燃性测试和详细性能研究。复合材料是通过使用双酚 A 甘油酯（1 甘油/苯酚）二丙烯酸酯（BPA.GDA）、乙二醇二甲基丙烯酸酯（EGDMA）和 kraft 木质素（木质素碱，L）在 UV 固化过程中获得的。为了评估木质素改性和阻燃化合物添加对所得生物复合材料耐热性的影响，进行了可燃性测试。磷酸（V）木质素以及二乙基乙烯基磷酸酯被用作阻燃添加剂。详细讨论了化学结构的变化（ATR-FTIR），以及不同添加剂对硬度、热（TG）和机械性能的影响。还研究了可燃性测试后的样品，以评估它们的热破坏情况。

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