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PFAS“永久化学物质”在珠穆朗玛峰上的沉积。

Deposition of PFAS 'forever chemicals' on Mt. Everest.

机构信息

Climate Change Institute, University of Maine, ME, USA; Jet Propulsion Laboratory, California Institute of Technology, CA, USA.

Climate Change Institute, University of Maine, ME, USA; School of Earth and Climate Sciences, University of Maine, ME, USA.

出版信息

Sci Total Environ. 2021 Mar 10;759:144421. doi: 10.1016/j.scitotenv.2020.144421. Epub 2020 Dec 17.

Abstract

Mt. Everest, one of the most coveted climbing mountains on earth, also contains the highest altitude chemical contamination on land. For the first time, meltwater and snow samples from Mt. Everest's Khumbu Glacier were analyzed for "forever chemicals" per- and polyfluoroalkyl substances (PFAS). Our research team utilized solid-phase extraction (SPE) and liquid chromatography-tandem mass spectrometry (LC-MS/MS) to identify pollutants sampled from Everest Base Camp, Camp 1, Camp 2, and Everest Balcony. From the 14 PFAS compounds tested for, we found perfluorooctanesulfonic acid (PFOS), perfluorooctanoic acid (PFOA), and perfluorohexanoic acid (PFHxA) in Mt. Everest snow and meltwater. The highest concentrations found were 26.14 ng/L and 10.34 ng/L PFOS at Base Camp and Camp 2, respectively. However, PFAS species were seen within 1-2 orders of magnitude in all sampling sites with detection, potentially suggesting a widespread presence on the mountain. Our samples are the highest altitude PFAS samples ever retrieved and indicate the need for further sampling both on Mt. Everest and in the below-glacier watershed.

摘要

珠穆朗玛峰是地球上最令人向往的登山胜地之一,也是陆地上海拔最高的化学污染区。首次对珠穆朗玛峰昆布冰川的融水和雪样进行了“永久性化学物质”全氟和多氟烷基物质 (PFAS) 分析。我们的研究团队使用固相萃取 (SPE) 和液相色谱-串联质谱 (LC-MS/MS) 从珠峰大本营、1 号营地、2 号营地和珠峰阳台采集的污染物进行了分析。在测试的 14 种 PFAS 化合物中,我们在珠穆朗玛峰的雪和融水中发现了全氟辛烷磺酸 (PFOS)、全氟辛酸 (PFOA) 和全氟己酸 (PFHxA)。在大本营和 2 号营地分别检测到的最高浓度分别为 26.14ng/L 和 10.34ng/L PFOS。然而,在所有采样点都检测到 PFAS 物质的浓度低 1-2 个数量级,这可能表明在山上广泛存在。我们的样本是迄今为止采集到的海拔最高的 PFAS 样本,表明需要进一步在珠穆朗玛峰及其冰川下游流域进行采样。

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