Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education), Department of Chemistry, Wuhan University, Wuhan 430072, China.
Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education), Department of Chemistry, Wuhan University, Wuhan 430072, China.
J Chromatogr A. 2021 Jan 25;1637:461810. doi: 10.1016/j.chroma.2020.461810. Epub 2020 Dec 15.
Recent progress of stir bar sorptive extraction (SBSE) in the past six years is reviewed. The preparation methods including electrodeposition, self-assembly, solvent exchange, physical magnetic adsorption and electrostatic spinning, for the coated stir bar are summarized and compared, specifically for a specific material for coatings fabrication, e.g., carbon-based materials and metal organic frameworks. The emerging materials (e.g., graphene, graphene oxide, carbon nanotubes, monolith, metal-organic frameworks and porous organic polymers) applied for coated stir bar fabrication are one of the focus of this review, along with their respective advantages in extraction process and application in trace analysis. The development and application of extraction apparatus of SBSE are also involved. Based on these information, the development status and prospects of SBSE as an efficient sample pretreatment technique in real sample analysis are discussed.
综述了近六年来搅拌棒吸附萃取（SBSE）的最新进展。总结并比较了涂层搅拌棒的制备方法，包括电沉积、自组装、溶剂交换、物理磁吸附和静电纺丝，具体针对特定材料的涂层制备，如碳基材料和金属有机骨架。本综述的重点之一是用于涂层搅拌棒制备的新兴材料（如石墨烯、氧化石墨烯、碳纳米管、整体材料、金属有机骨架和多孔有机聚合物），以及它们在萃取过程中的各自优势及其在痕量分析中的应用。还涉及了 SBSE 萃取装置的开发和应用。基于这些信息，讨论了 SBSE 作为一种有效的样品预处理技术在实际样品分析中的发展现状和前景。
