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金属骨架促进了两相耐用的疏冰层。

Metallic skeleton promoted two-phase durable icephobic layers.

作者信息

Wang Jie, Wu Mengjuan, Liu Junpeng, Xu Fang, Hussain Tanvir, Scotchford Colin, Hou Xianghui

机构信息

Faculty of Engineering, University of Nottingham, University Park, Nottingham NG7 2RD, UK.

Faculty of Engineering, University of Nottingham, University Park, Nottingham NG7 2RD, UK.

出版信息

J Colloid Interface Sci. 2021 Apr;587:47-55. doi: 10.1016/j.jcis.2020.12.027. Epub 2020 Dec 15.

Abstract

HYPOTHESIS

The accretion of ice on component surfaces often causes severe impacts or accidents in modern industries. Applying icephobic surface is considered as an effective solution to minimise the hazards. However, the durability of the current icephobic surface and coatings for long-term service remains a great challenge. Therefore, it is indeed to develop new durable material structures with great icephobic performance.

EXPERIMENTS

A new design concept of combining robust porous metallic skeletons and icephobic filling was proposed. Nickel/polydimethylsiloxane (PDMS) two-phase layer was prepared using porous Ni foam skeletons impregnated with PDMS as filling material by a two-step method.

FINDINGS

Good icephobicity and mechanical durability have been verified. Under external force, micro-cracks could easily initiate at the ice/solid interface due to the small surface cavities and the difference of local elastic modulus between the ice and PDMS, which would promote the ice fracture and thus lead to low ice adhesion strength. The surface morphology and icephobicity almost remain unchanged after water-sand erosion, showing greatly improved mechanical durability. By combining the advantages of the mechanical durability of porous Ni skeleton and the icephobicity of PDMS matrix, the Ni foam/PDMS two-phase layer demonstrates great potentials for ice protection with long-term service time.

摘要

假设

部件表面结冰在现代工业中常常会导致严重影响或事故。应用憎冰表面被认为是将危害降至最低的有效解决方案。然而,当前憎冰表面及涂层长期使用的耐久性仍然是一个巨大挑战。因此,开发具有优异憎冰性能的新型耐用材料结构确实很有必要。

实验

提出了一种将坚固的多孔金属骨架与憎冰填充物相结合的新设计理念。采用两步法,以浸渍有聚二甲基硅氧烷(PDMS)的多孔泡沫镍骨架作为填充材料,制备了镍/聚二甲基硅氧烷(PDMS)两相层。

研究结果

已验证其具有良好的憎冰性和机械耐久性。在外力作用下,由于表面空洞较小以及冰与PDMS之间局部弹性模量的差异,微裂纹很容易在冰/固体界面处萌生,这会促进冰的破裂,从而导致低冰粘附强度。水砂冲蚀后,表面形貌和憎冰性几乎保持不变,显示出机械耐久性有了极大提高。通过结合多孔镍骨架的机械耐久性和PDMS基体的憎冰性优点,泡沫镍/PDMS两相层在长期使用时展现出巨大的防冰潜力。

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