Metal-Organic Framework Decorated Cuprous Oxide Nanowires for Long-lived Charges Applied in Selective Photocatalytic CO Reduction to CH.

Improving the stability of cuprous oxide (Cu O) is imperative to its practical applications in artificial photosynthesis. In this work, Cu O nanowires are encapsulated by metal-organic frameworks (MOFs) of Cu (BTC) (BTC=1,3,5-benzene tricarboxylate) using a surfactant-free method. Such MOFs not only suppress the water vapor-induced corrosion of Cu O but also facilitate charge separation and CO uptake, thus resulting in a nanocomposite representing 1.9 times improved activity and stability for selective photocatalytic CO reduction into CH under mild reaction conditions. Furthermore, direct transfer of photogenerated electrons from the conduction band of Cu O to the LUMO level of non-excited Cu (BTC) has been evidenced by time-resolved photoluminescence. This work proposes an effective strategy for CO conversion by a synergy of charge separation and CO adsorption, leading to the enhanced photocatalytic reaction when MOFs are integrated with metal oxide photocatalyst.