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[河南省饮用水源中新型持久性有机污染物的分布及生态风险评估]

[Distribution and Ecological Risk Assessment of PPCPs in Drinking Water Sources of Henan Province].

作者信息

Zhou Ying, Wu Dong-Hai, Lu Guang-Hua, Yao Jing-Jing, Wei Lei, Han Feng

机构信息

Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, Hohai University, Nanjing 210098, China.

Water Conservancy Project & Civil Engineering College, Tibet Agriculture & Animal Husbandry University, Linzhi 860000, China.

出版信息

Huan Jing Ke Xue. 2021 Jan 8;42(1):159-165. doi: 10.13227/j.hjkx.202005239.

Abstract

The occurrence of emerging pollutants pharmaceuticals and personal care products (PPCPs) in aquatic environments has potential adverse effects on aquatic organisms, and the presence of PPCPs in drinking water sources is very likely to cause harm to human health. The PPCPs pollution in five typical drinking water sources in Henan province was investigated. Moreover, the source of pollutants was analyzed and the relevant ecological risks were evaluated. The results showed that the cumulative concentrations of 20 PPCPs at different sampling sites ranged from 24.2 to 317.6 ng·L. Caffeine (CFI) was the highest level contaminant, with the concentration up to 186.4 ng·L, followed by sulfamethoxazole (SMX) and ofloxacin (OFC), with detected concentrations up to 70.8 ng·L and 24.2 ng·L, respectively. The pollution of PPCPs in Heigangkou drinking water sources was higher than those of other drinking water sources. The comparation of the labile indicator CFI and the conservative indicator carbamazepine (CBZ) concentrations implies that the pollutions from the upstream water and around scattered domestic sewage might be responsible for the PPCPs present in these drinking water sources. The risk quotient (RQ) calculation results indicated that the detected PPCPs in 5 drinking water sources have moderate to high risks to algae, while low to moderate risks to invertebrates and fish. Therefore, attention should be paid to relevant pollution control.

摘要

新兴污染物——药品和个人护理产品(PPCPs)在水生环境中的出现,对水生生物具有潜在的不利影响,并且饮用水源中PPCPs的存在极有可能对人类健康造成危害。对河南省五个典型饮用水源中的PPCPs污染情况进行了调查。此外,分析了污染物来源并评估了相关生态风险。结果表明,不同采样点20种PPCPs的累积浓度范围为24.2至317.6 ng·L。咖啡因(CFI)是污染水平最高的污染物,浓度高达186.4 ng·L,其次是磺胺甲恶唑(SMX)和氧氟沙星(OFC),检测浓度分别高达70.8 ng·L和24.2 ng·L。黑港口饮用水源中PPCPs的污染程度高于其他饮用水源。不稳定指标CFI和保守指标卡马西平(CBZ)浓度的比较表明,上游水体污染和周边分散生活污水可能是这些饮用水源中PPCPs的污染来源。风险商数(RQ)计算结果表明,5个饮用水源中检测到的PPCPs对藻类具有中到高风险,对无脊椎动物和鱼类具有低到中风险。因此,应关注相关污染控制。

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