Jo Sumi, Whitmore Lawrence, Woo Sangkyu, Aramburu Ainhoa Urrutia, Letzig Dietmar, Yi Sangbong
Magnesium Innovation Centre (MagIC), Helmholtz-Zentrum Geesthacht, Max-Planck-Str. 1, 21502, Geesthacht, Germany.
Department of Chemistry and Physics of Materials, Salzburg University, Jakob-Haringer-Str. 2a, 5020, Salzburg, Austria.
Sci Rep. 2020 Dec 29;10(1):22413. doi: 10.1038/s41598-020-79390-z.
Age-hardenability and corresponding improvement of the mechanical properties of Mg-1Al-0.7Ca and Mg-1Al-0.7Ca-0.7Y alloy sheets are addressed with respect to the microstructure and texture evolution during thermomechanical treatments. A fine grain structure and weak texture with the basal pole split into the sheet transverse direction are retained in the Mg-1Al-0.7Ca-0.7Y sheet even after the homogenization at 500 °C, due to the grain boundary pinning by Y-containing precipitates possessing a high thermal stability. Contrarily, the Mg-1Al-0.7Ca sheet shows a coarse microstructure and basal-type texture after the homogenization. The peak-aged condition is attained after the aging at 250 °C for 1800 s of both homogenized sheets, while the Y-containing sheet shows a higher hardness than the Mg-1Al-0.7Ca sheet. TEM analysis and thermodynamic calculation show the formation of metastable precipitates composed of Al, Ca, Y and Mg in the Mg-1Al-0.7Ca-0.7Y sheet at the homogenized and peak-aged conditions. A significant increase in the yield strength is obtained in the peak-aged condition from 162 MPa after the homogenization to 244 MPa, which arises from the increased size and number density of the precipitates. The high age-hardenability of the Mg-1Al-0.7Ca-0.7Y sheet attributes to the superior mechanical properties with an improved ductility promoted by the weak texture.
针对热机械处理过程中的微观结构和织构演变,研究了Mg-1Al-0.7Ca和Mg-1Al-0.7Ca-0.7Y合金板材的时效硬化能力及相应的力学性能改善情况。由于具有高热稳定性的含Y析出相钉扎晶界,即使在500℃均匀化处理后,Mg-1Al-0.7Ca-0.7Y板材仍保留了细小的晶粒结构和基面极分裂成板材横向的弱织构。相反,Mg-1Al-0.7Ca板材在均匀化后呈现出粗大的微观结构和基面型织构。两种均匀化板材在250℃时效1800s后达到峰值时效状态,而含Y板材的硬度高于Mg-1Al-0.7Ca板材。TEM分析和热力学计算表明,在均匀化和峰值时效条件下,Mg-1Al-0.7Ca-0.7Y板材中形成了由Al、Ca、Y和Mg组成的亚稳析出相。在峰值时效状态下,屈服强度从均匀化后的162MPa显著提高到244MPa,这是由于析出相尺寸和数量密度增加所致。Mg-1Al-0.7Ca-0.7Y板材的高时效硬化能力归因于其优异的力学性能以及由弱织构促进的延展性改善。