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基于石墨烯的砷修复策略的最新进展

Recent Advances of Graphene-Based Strategies for Arsenic Remediation.

作者信息

Foti Claudia, Mineo Placido Giuseppe, Nicosia Angelo, Scala Angela, Neri Giulia, Piperno Anna

机构信息

Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Messina, Italy.

Department of Chemical Sciences, University of Catania, Catania, Italy.

出版信息

Front Chem. 2020 Dec 14;8:608236. doi: 10.3389/fchem.2020.608236. eCollection 2020.

Abstract

The decontamination of water containing toxic metals is a challenging problem, and in the last years many efforts have been undertaken to discover efficient, cost-effective, robust, and handy technology for the decontamination of downstream water without endangering human health. According to the World Health Organization (WHO), 180 million people in the world have been exposed to toxic levels of arsenic from potable water. To date, a variety of techniques has been developed to maintain the arsenic concentration in potable water below the limit recommended by WHO (10 μg/L). Recently, a series of technological advancements in water remediation has been obtained from the rapid development of nanotechnology-based strategies that provide a remarkable control over nanoparticle design, allowing the tailoring of their properties toward specific applications. Among the plethora of nanomaterials and nanostructures proposed in the remediation field, graphene-based materials (G), due to their unique physico-chemical properties, surface area, size, shape, ionic mobility, and mechanical flexibility, are proposed for the development of reliable tools for water decontamination treatments. Moreover, an emerging class of 3D carbon materials characterized by the intrinsic properties of G together with new interesting physicochemical properties, such as high porosity, low density, unique electrochemical performance, has been recently proposed for water decontamination. The main design criteria used to develop remediation nanotechnology-based strategies have been reviewed, and special attention has been reserved for the advances of magnetic G and for nanostructures employed in the fabrication of membrane filtration.

摘要

含重金属的水的净化是一个具有挑战性的问题,在过去几年中,人们付出了很多努力来寻找高效、经济高效、稳健且便捷的技术,以净化下游水且不危及人类健康。根据世界卫生组织(WHO)的数据,全球有1.8亿人因饮用水接触到有毒水平的砷。迄今为止,已经开发出了多种技术来将饮用水中的砷浓度维持在WHO建议的限值(10μg/L)以下。最近,基于纳米技术的策略迅速发展,在水修复方面取得了一系列技术进步,这些策略能够对纳米颗粒设计进行显著控制,从而使其性能能够针对特定应用进行定制。在修复领域提出的众多纳米材料和纳米结构中,基于石墨烯的材料(G)因其独特的物理化学性质、表面积、尺寸、形状、离子迁移率和机械柔韧性,被提议用于开发可靠的水净化处理工具。此外,最近还提出了一类新兴的3D碳材料,其具有G的固有特性以及新的有趣物理化学性质,如高孔隙率、低密度、独特的电化学性能,用于水净化。本文综述了用于开发基于修复纳米技术的策略的主要设计标准,并特别关注了磁性G的进展以及用于制造膜过滤的纳米结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e02/7767874/1f913e20a946/fchem-08-608236-g0001.jpg

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