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中红外多模态吸收设计:一种金属-电介质-金属方法。

Design of Multimodal Absorption in the Mid-IR: A Metal Dielectric Metal Approach.

作者信息

Pech-May Nelson W, Retsch Markus

机构信息

Department of Chemistry, Physical Chemistry I, University of Bayreuth, Universitätsstr. 30, Bayreuth 95447, Germany.

Bundesanstalt für Materialforschung und -prüfung (BAM), Berlin 12200, Germany.

出版信息

ACS Appl Mater Interfaces. 2021 Jan 13;13(1):1921-1929. doi: 10.1021/acsami.0c18160. Epub 2021 Jan 4.

Abstract

Specific control on the mid-infrared (mid-IR) emission properties is attracting increasing attention for thermal camouflage and passive cooling applications. Metal-dielectric-metal (MDM) structures are well known to support strong magnetic polariton resonances in the optical and near-infrared range. We extend the current understanding of such an MDM structure by specifically designing Au disc arrays on top of ZnS-Au-Si substrates and pushing their resonances to the mid-IR regime. Therefore, we combine fabrication via lift-off photolithography with the finite element method and an inductance-capacitance model. With this combination of techniques, we demonstrate that the magnetic polariton resonance of the first order strongly depends on the individual disc diameter. Furthermore, the fabrication of multiple discs within one unit cell allows a linear combination of the fundamental resonances to conceive broadband absorptance. Quite importantly, even in mixed resonator cases, the absorptance spectra can be fully described by a superposition of the individual disc properties. Our contribution provides rational guidance to deterministically design mid-IR emitting materials with specific narrow- or broadband properties.

摘要

对中红外(mid-IR)发射特性的特定控制在热伪装和被动冷却应用中引起了越来越多的关注。众所周知,金属-电介质-金属(MDM)结构在光学和近红外范围内支持强磁极化子共振。我们通过在ZnS-Au-Si衬底上专门设计金盘阵列并将其共振推向中红外区域,扩展了对这种MDM结构的当前认识。因此,我们将剥离光刻制造技术与有限元方法和电感-电容模型相结合。通过这种技术组合,我们证明了一阶磁极化子共振强烈依赖于单个盘的直径。此外,在一个晶胞内制造多个盘允许对基本共振进行线性组合以构思宽带吸收率。非常重要的是,即使在混合谐振器的情况下,吸收率光谱也可以通过单个盘特性的叠加来完全描述。我们的贡献为确定性地设计具有特定窄带或宽带特性的中红外发射材料提供了合理的指导。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2697/7877563/c2fb2d92ab41/am0c18160_0002.jpg

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