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双原子分子离子的光致破坏:实验室和天体物理应用。

Photodestruction of Diatomic Molecular Ions: Laboratory and Astrophysical Application.

机构信息

Institute of Physics Belgrade, Belgrade University, Pregrevica 118, 11080 Belgrade, Serbia.

Astronomical Observatory, Volgina 7, 11060 Belgrade, Serbia.

出版信息

Molecules. 2020 Dec 31;26(1):151. doi: 10.3390/molecules26010151.

DOI:10.3390/molecules26010151
PMID:33396268
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7795095/
Abstract

In this work, the processes of photodissociation of some diatomic molecular ions are investigated. The partial photodissociation cross-sections for the individual rovibrational states of the diatomic molecular ions, which involves alkali metals, as well as corresponding data on molecular species and molecular state characterizations, are calculated. Also, the average cross-section and the corresponding spectral absorption rate coefficients for those small molecules are presented in tabulated form as a function of wavelengths and temperatures. The presented results can be of interest for laboratory plasmas as well as for the research of chemistry of different stellar objects with various astrophysical plasmas.

摘要

在这项工作中,研究了一些双原子分子离子的光解离过程。计算了涉及碱金属的双原子分子离子的各个转动和振动状态的部分光解离截面,以及相应的分子种类和分子状态特征数据。此外,还以表格形式给出了这些小分子的平均截面和相应的光谱吸收速率系数,作为波长和温度的函数。所提出的结果不仅对实验室等离子体,而且对具有各种天体等离子体的不同恒星物体化学的研究都具有重要意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/6fa5fe557e70/molecules-26-00151-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/7ad4b63798e9/molecules-26-00151-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/2fa31926e75a/molecules-26-00151-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/10718e8cee50/molecules-26-00151-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/699906eba7c1/molecules-26-00151-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/b97215679fa8/molecules-26-00151-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/6fa5fe557e70/molecules-26-00151-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/7ad4b63798e9/molecules-26-00151-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/2fa31926e75a/molecules-26-00151-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/10718e8cee50/molecules-26-00151-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/699906eba7c1/molecules-26-00151-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/b97215679fa8/molecules-26-00151-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322e/7795095/6fa5fe557e70/molecules-26-00151-g006.jpg

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The Role of State-of-the-Art Quantum-Chemical Calculations in Astrochemistry: Formation Route and Spectroscopy of Ethanimine as a Paradigmatic Case.量子化学计算在天体化学中的作用:以乙亚胺为例的形成途径和光谱学。
Molecules. 2020 Jun 22;25(12):2873. doi: 10.3390/molecules25122873.
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Laser-Plasma Spectroscopy of Hydroxyl with Applications.
羟基的激光等离子体光谱及其应用
Molecules. 2020 Feb 22;25(4):988. doi: 10.3390/molecules25040988.
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The Plasma Spectroscopic Study of Dergaon Meteorite, India.印度德高恩陨石的等离子体光谱研究。
Molecules. 2020 Feb 22;25(4):984. doi: 10.3390/molecules25040984.
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Laser-Plasma Spatiotemporal Cyanide Spectroscopy and Applications.激光等离子体时空氰化物光谱学及应用。
Molecules. 2020 Jan 31;25(3):615. doi: 10.3390/molecules25030615.
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Contribution of synchrotron radiation to photoactivation studies of biomolecular ions in the gas phase.同步辐射对气相生物分子离子光致活性研究的贡献。
Mass Spectrom Rev. 2014 Nov-Dec;33(6):424-41. doi: 10.1002/mas.21398. Epub 2013 Dec 17.
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Ab initio many-electron study for the low-lying states of the alkali hydride cations in the adiabatic representation.从头算多电子研究碱金属氢化物阳离子在绝热表象中的低能态。
J Chem Phys. 2012 Mar 28;136(12):124304. doi: 10.1063/1.3695997.
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